Atomically precise Au(144)(SR)(60) nanoclusters (R = Et, Pr) are capped by 12 distinct ligand types of 5-fold equivalence and display gigantic diastereotopic effects

For two decades, Au(144)(SR)(60) has been one of the most studied and used thiolate (SR) protected gold nanoclusters. In many ways, however, it proved to be a challenging and elusive case, also because of the difficulties in solving its structure by single-crystal X-ray crystallography. We used very...

Descripción completa

Detalles Bibliográficos
Autores principales: Dainese, Tiziano, Agrachev, Mikhail, Antonello, Sabrina, Badocco, Denis, Black, David M., Fortunelli, Alessandro, Gascón, José A., Stener, Mauro, Venzo, Alfonso, Whetten, Robert L., Maran, Flavio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6301266/
https://www.ncbi.nlm.nih.gov/pubmed/30647884
http://dx.doi.org/10.1039/c8sc04092c

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6301266/
https://www.ncbi.nlm.nih.gov/pubmed/30647884
http://dx.doi.org/10.1039/c8sc04092c

Ejemplares similares