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Embryonic brass: pseudo two electron Cu/Zn clusters
The isoelectronic M(7) clusters [Cu(3)Zn(4)](Cp*)(5) (1) and {[Cu(2)Zn(5)](Cp*)(5)}(+) (2) are described. While 1 can be isolated only as a minor side product from the reaction of Cu(CH(3)CO(2)) with equimolar amounts of [Zn(2)Cp*(2)] with the trigonal cluster [CuZn(2)](Cp*)(3) as the major product,...
Autores principales: | , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6301272/ https://www.ncbi.nlm.nih.gov/pubmed/30647885 http://dx.doi.org/10.1039/c8sc03902j |