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Chemical Exchange Saturation Transfer in Chemical Reactions: A Mechanistic Tool for NMR Detection and Characterization of Transient Intermediates

[Image: see text] The low sensitivity of NMR and transient key intermediates below detection limit are the central problems studying reaction mechanisms by NMR. Sensitivity can be enhanced by hyperpolarization techniques such as dynamic nuclear polarization or the incorporation/interaction of specia...

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Detalles Bibliográficos
Autores principales: Lokesh, N., Seegerer, Andreas, Hioe, Johnny, Gschwind, Ruth M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6301330/
https://www.ncbi.nlm.nih.gov/pubmed/29336150
http://dx.doi.org/10.1021/jacs.7b12343