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Freezing copper as a noble metal–like catalyst for preliminary hydrogenation

The control of product distribution in a multistep catalytic selective hydrogenation reaction is challenging. For instance, the deep hydrogenation of dimethyl oxalate (DMO) is inclined to proceed over Cu/SiO(2) catalysts because of inevitable coexistence of Cu(+) and Cu(0), leading to hard acquisiti...

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Detalles Bibliográficos
Autores principales: Sun, Jian, Yu, Jiafeng, Ma, Qingxiang, Meng, Fanqiong, Wei, Xiaoxuan, Sun, Yannan, Tsubaki, Noritatsu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Association for the Advancement of Science 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6303123/
https://www.ncbi.nlm.nih.gov/pubmed/30588490
http://dx.doi.org/10.1126/sciadv.aau3275