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Freezing copper as a noble metal–like catalyst for preliminary hydrogenation
The control of product distribution in a multistep catalytic selective hydrogenation reaction is challenging. For instance, the deep hydrogenation of dimethyl oxalate (DMO) is inclined to proceed over Cu/SiO(2) catalysts because of inevitable coexistence of Cu(+) and Cu(0), leading to hard acquisiti...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Association for the Advancement of Science
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6303123/ https://www.ncbi.nlm.nih.gov/pubmed/30588490 http://dx.doi.org/10.1126/sciadv.aau3275 |