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Desymmetrization of meso-bisphosphates using copper catalysis and alkylzirconocene nucleophiles
The desymmetrization of meso-compounds is a useful synthetic method, as illustrated by numerous applications of this strategy in natural product synthesis. Cu-catalyzed allylic desymmetrizations enable the enantioselective formation of carbon-carbon bonds, but these transformations are limited in su...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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Nature Publishing Group UK
2019
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6318275/ https://www.ncbi.nlm.nih.gov/pubmed/30604753 http://dx.doi.org/10.1038/s41467-018-07871-x |