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pH effects on the electrochemical reduction of CO((2)) towards C(2) products on stepped copper

We present a microkinetic model for CO((2)) reduction (CO((2))R) on Cu(211) towards C(2) products, based on energetics estimated from an explicit solvent model. We show that the differences in both Tafel slopes and pH dependence for C(1) vs C(2) activity arise from differences in their multi-step me...

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Detalles Bibliográficos
Autores principales:	Liu, Xinyan, Schlexer, Philomena, Xiao, Jianping, Ji, Yongfei, Wang, Lei, Sandberg, Robert B., Tang, Michael, Brown, Kristopher S., Peng, Hongjie, Ringe, Stefan, Hahn, Christopher, Jaramillo, Thomas F., Nørskov, Jens K., Chan, Karen
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Nature Publishing Group UK 2019
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6318338/ https://www.ncbi.nlm.nih.gov/pubmed/30604776 http://dx.doi.org/10.1038/s41467-018-07970-9

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