Exploiting the Electronic Tuneability of Carboranes as Supports for Frustrated Lewis Pairs

The first example of a carborane with a catecholborolyl substituent, [1-Bcat-2-Ph-closo-1,2-C(2)B(10)H(10)] (1), has been prepared and characterized and shown to act as the Lewis acid component of an intermolecular frustrated Lewis pair in catalyzing a Michael addition. In combination with B(C(6)F(5...

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Detalles Bibliográficos
Autores principales: Benton, Amanda, Copeland, Zachariah, M. Mansell, Stephen, M. Rosair, Georgina, Welch, Alan J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2018
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6321043/
https://www.ncbi.nlm.nih.gov/pubmed/30486434
http://dx.doi.org/10.3390/molecules23123099

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6321043/
https://www.ncbi.nlm.nih.gov/pubmed/30486434
http://dx.doi.org/10.3390/molecules23123099

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