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Exploiting the Electronic Tuneability of Carboranes as Supports for Frustrated Lewis Pairs
The first example of a carborane with a catecholborolyl substituent, [1-Bcat-2-Ph-closo-1,2-C(2)B(10)H(10)] (1), has been prepared and characterized and shown to act as the Lewis acid component of an intermolecular frustrated Lewis pair in catalyzing a Michael addition. In combination with B(C(6)F(5...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
MDPI
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6321043/ https://www.ncbi.nlm.nih.gov/pubmed/30486434 http://dx.doi.org/10.3390/molecules23123099 |