TfOH-Promoted Reaction of 2,4-Diaryl-1,1,1-Trifluorobut-3-yn-2-oles with Arenes: Synthesis of 1,3-Diaryl-1-CF(3)-Indenes and Versatility of the Reaction Mechanisms

The TfOH-mediated reactions of 2,4-diaryl-1,1,1-trifluorobut-3-yn-2-oles (CF(3)-substituted diaryl propargyl alcohols) with arenes in CH(2)Cl(2) afford 1,3-diaryl-1-CF(3)-indenes in yields up to 84%. This new process for synthesis of such CF(3)-indenes is complete at room temperature within one hour...

Descripción completa

Detalles Bibliográficos
Autores principales: Zerov, Aleksey V., Kazakova, Anna N., Boyarskaya, Irina A., Panikorovskii, Taras L., Suslonov, Vitalii V., Khoroshilova, Olesya V., Vasilyev, Aleksander V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2018
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6321356/
https://www.ncbi.nlm.nih.gov/pubmed/30477271
http://dx.doi.org/10.3390/molecules23123079

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6321356/
https://www.ncbi.nlm.nih.gov/pubmed/30477271
http://dx.doi.org/10.3390/molecules23123079

Ejemplares similares