[2+2+2] Annulation of N-(1-Naphthyl)acetamide with Two Alkynoates via Cleavage of Adjacent C–H and C–N Bonds Catalyzed by an Electron-Deficient Rhodium(III) Complex

It has been established that an electron-deficient cationic Cp(E)-rhodium(III) complex catalyzes the non-oxidative [2+2+2] annulation of N-(1-naphthyl)acetamide with two alkynoates via cleavage of the adjacent C–H and C–N bonds to give densely substituted phenanthrenes under mild conditions (at 40 °...

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Detalles Bibliográficos
Autores principales: Terasawa, Jyunichi, Shibata, Yu, Fukui, Miho, Tanaka, Ken
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2018
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6321495/
https://www.ncbi.nlm.nih.gov/pubmed/30558193
http://dx.doi.org/10.3390/molecules23123325

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6321495/
https://www.ncbi.nlm.nih.gov/pubmed/30558193
http://dx.doi.org/10.3390/molecules23123325

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