Chloro- and Dichloro-methylsulfonyl Nitrenes: Spectroscopic Characterization, Photoisomerization, and Thermal Decomposition

Chloro- and dichloro-methylsulfonyl nitrenes, CH(2)ClS(O)(2)N and CHCl(2)S(O)(2)N, have been generated from UV laser photolysis (193 and 266 nm) of the corresponding sulfonyl azides CH(2)ClS(O)(2)N(3) and CHCl(2)S(O)(2)N(3), respectively. Both nitrenes have been characterized with matrix-isolation I...

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Detalles Bibliográficos
Autores principales: Yang, Yang, Chu, Xianxu, Lu, Yan, Abe, Manabu, Zeng, Xiaoqing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2018
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6321523/
https://www.ncbi.nlm.nih.gov/pubmed/30551679
http://dx.doi.org/10.3390/molecules23123312

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6321523/
https://www.ncbi.nlm.nih.gov/pubmed/30551679
http://dx.doi.org/10.3390/molecules23123312

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