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Chloro- and Dichloro-methylsulfonyl Nitrenes: Spectroscopic Characterization, Photoisomerization, and Thermal Decomposition
Chloro- and dichloro-methylsulfonyl nitrenes, CH(2)ClS(O)(2)N and CHCl(2)S(O)(2)N, have been generated from UV laser photolysis (193 and 266 nm) of the corresponding sulfonyl azides CH(2)ClS(O)(2)N(3) and CHCl(2)S(O)(2)N(3), respectively. Both nitrenes have been characterized with matrix-isolation I...
Autores principales: | Yang, Yang, Chu, Xianxu, Lu, Yan, Abe, Manabu, Zeng, Xiaoqing |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6321523/ https://www.ncbi.nlm.nih.gov/pubmed/30551679 http://dx.doi.org/10.3390/molecules23123312 |
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