Cargando…

Crystal structures of two PCN pincer iridium complexes and one PCP pincer carbodi­phospho­rane iridium inter­mediate: substitution of one phosphine moiety of a carbodi­phospho­rane by an organic azide

The structure of [Ir{(4-Cl-C(6)H(4)N(3))C(dppm)-κ(3) P,C,N}(dppm-κ(2) P,P′)]Cl·1.5CH(2)Cl(2)·0.5C(7)H(8) (C(57)H(48)Cl(2)IrN(3)P(4)·1.5CH(2)Cl(2)·0.5C(7)H(8)) (2), dppm = bis­(di­phenyl­phosphino)methane {systematic name: [7-(4-chloro­phen­yl)-1,1,3,3-tetra­phenyl-5,6,7-tri­aza-κN (7)-1,3λ(4)-diphos...

Descripción completa

Detalles Bibliográficos
Autores principales: Partl, Gabriel Julian, Nussbaumer, Felix, Schuh, Walter, Kopacka, Holger, Wurst, Klaus, Peringer, Paul
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6323870/
https://www.ncbi.nlm.nih.gov/pubmed/30713738
http://dx.doi.org/10.1107/S2056989018017644