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Crystal structures of two PCN pincer iridium complexes and one PCP pincer carbodiphosphorane iridium intermediate: substitution of one phosphine moiety of a carbodiphosphorane by an organic azide
The structure of [Ir{(4-Cl-C(6)H(4)N(3))C(dppm)-κ(3) P,C,N}(dppm-κ(2) P,P′)]Cl·1.5CH(2)Cl(2)·0.5C(7)H(8) (C(57)H(48)Cl(2)IrN(3)P(4)·1.5CH(2)Cl(2)·0.5C(7)H(8)) (2), dppm = bis(diphenylphosphino)methane {systematic name: [7-(4-chlorophenyl)-1,1,3,3-tetraphenyl-5,6,7-triaza-κN (7)-1,3λ(4)-diphos...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6323870/ https://www.ncbi.nlm.nih.gov/pubmed/30713738 http://dx.doi.org/10.1107/S2056989018017644 |