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Syntheses and crystal structures of [Ir(III){C(CHCO(2)Et)(dppm)(2)-κ(4) P,C,C′,P′}ClH]Cl·2.75CH(2)Cl(2) and its derivatives, [Ir(III){C(CHCO(2)Et)(dppm)(2)-κ(4) P,C,C′,P′}(CH(2)CO(2)Et)Cl]Cl·CH(3)OH·0.5H(2)O, [Ir(III){C(CHCO(2)Et)(dppm)(2)-κ(4) P,C,C′,P′}Cl(2)]Cl·CH(3)OH·2H(2)O and [Ir(III){C(CHCO(2)Et)(dppm)(2)-κ(4) P,C,C′,P′}(CH(2)CO(2)Et)(CO)]Cl(2)·2CH(2)Cl(2)·1.5H(2)O
The common feature of the four iridium(III) salt complexes, (bis{[(diphenylphosphanyl)methyl]diphenylphosphanylidene}(ethoxyoxoethanylidene)methane-κ(4) P,C,C′,P′)chloridohydridoiridium(III) chloride methylene chloride 2.75-solvate (4), (bis{[(diphenylphosphanyl)methyl]diphenylph...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6323871/ https://www.ncbi.nlm.nih.gov/pubmed/30713725 http://dx.doi.org/10.1107/S2056989018017024 |