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Syntheses and crystal structures of [Ir(III){C(CHCO(2)Et)(dppm)(2)-κ(4) P,C,C′,P′}ClH]Cl·2.75CH(2)Cl(2) and its derivatives, [Ir(III){C(CHCO(2)Et)(dppm)(2)-κ(4) P,C,C′,P′}(CH(2)CO(2)Et)Cl]Cl·CH(3)OH·0.5H(2)O, [Ir(III){C(CHCO(2)Et)(dppm)(2)-κ(4) P,C,C′,P′}Cl(2)]Cl·CH(3)OH·2H(2)O and [Ir(III){C(CHCO(2)Et)(dppm)(2)-κ(4) P,C,C′,P′}(CH(2)CO(2)Et)(CO)]Cl(2)·2CH(2)Cl(2)·1.5H(2)O

The common feature of the four iridium(III) salt complexes, (bis­{[(di­phenyl­phosphan­yl)meth­yl]di­phenyl­phosphanyl­idene}(eth­oxy­oxoethanyl­idene)methane-κ(4) P,C,C′,P′)chlorido­hydridoiridium(III) chloride methyl­ene chloride 2.75-solvate (4), (bis­{[(di­phenyl­phosphan­yl)meth­yl]di­phenyl­ph...

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Detalles Bibliográficos
Autores principales: Schlapp-Hackl, Inge, Falschlunger, Christoph, Zauner, Kathrin, Schuh, Walter, Kopacka, Holger, Wurst, Klaus, Peringer, Paul
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6323871/
https://www.ncbi.nlm.nih.gov/pubmed/30713725
http://dx.doi.org/10.1107/S2056989018017024