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Synthesis of new Ln(4)(Al(2)O(6)F(2))O(2) (Ln = Sm, Eu, Gd) phases with a cuspidine-related structure

The first fluorination of the cuspidine-related phases of Ln(4)(Al(2)O(7)□)O(2) (where Ln = Sm, Eu, Gd) is reported. A low-temperature reaction with poly(vinyl­idene difluoride) lead to the fluorine being substituted in place of oxygen and inserted into the vacant position between the dialuminate gr...

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Detalles Bibliográficos
Autores principales: Morán-Ruiz, Aroa, Wain-Martin, Aritza, Orera, Alodia, Sanjuán, María Luisa, Larrañaga, Aitor, Slater, Peter R., Arriortua, Maribel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6327175/
https://www.ncbi.nlm.nih.gov/pubmed/30713710
http://dx.doi.org/10.1107/S205225251801744X