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Mechanistic investigation into the C(sp(3))–H acetoxylation of morpholinones
The study of a selective palladium(ii)-catalyzed C(sp(3))–H acetoxylation reaction on a class of cyclic alkyl amines is reported. Computational modelling and kinetic studies were used to provide support for a mechanism involving selective C–O bond formation from a γ-aminoalkyl-Pd(iv) intermediate. T...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6331033/ https://www.ncbi.nlm.nih.gov/pubmed/30713620 http://dx.doi.org/10.1039/c8sc03434f |