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Mechanistic investigation into the C(sp(3))–H acetoxylation of morpholinones

The study of a selective palladium(ii)-catalyzed C(sp(3))–H acetoxylation reaction on a class of cyclic alkyl amines is reported. Computational modelling and kinetic studies were used to provide support for a mechanism involving selective C–O bond formation from a γ-aminoalkyl-Pd(iv) intermediate. T...

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Detalles Bibliográficos
Autores principales:	Buettner, Cornelia S., Willcox, Darren, Chappell, Ben. G. N., Gaunt, Matthew J.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2018
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6331033/ https://www.ncbi.nlm.nih.gov/pubmed/30713620 http://dx.doi.org/10.1039/c8sc03434f

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