Iridium-Catalyzed Asymmetric Ring-Opening of Oxabenzonorbornadienes with N-Substituted Piperazine Nucleophiles

Iridium-catalyzed asymmetric ring-opening of oxabenzonorbornadienes with N-substituted piperazines was described. The reaction afforded the corresponding ring-opening products in high yields and moderate enantioselectivities in the presence of 2.5 mol % [Ir(COD)Cl](2) and 5.0 mol % (S)-p-Tol-BINAP....

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Detalles Bibliográficos
Autores principales: Yang, Wen, Luo, Renshi, Yang, Dingqiao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2015
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6332042/
https://www.ncbi.nlm.nih.gov/pubmed/26633315
http://dx.doi.org/10.3390/molecules201219748

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6332042/
https://www.ncbi.nlm.nih.gov/pubmed/26633315
http://dx.doi.org/10.3390/molecules201219748

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