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Characteristic Conformation of Mosher’s Amide Elucidated Using the Cambridge Structural Database

Conformations of the crystalline 3,3,3-trifluoro-2-methoxy-2-phenylpropanamide derivatives (MTPA amides) deposited in the Cambridge Structural Database (CSD) were examined statistically as R(acid)-enantiomers. The majority of dihedral angles (48/58, ca. 83%) of the amide carbonyl groups and the trif...

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Detalles Bibliográficos
Autores principales: Ichikawa, Akio, Ono, Hiroshi, Mikata, Yuji
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6332137/
https://www.ncbi.nlm.nih.gov/pubmed/26193245
http://dx.doi.org/10.3390/molecules200712880