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Synthesis of New 2-Halo-2-(1H-tetrazol-5-yl)-2H-azirines via a Non-Classical Wittig Reaction

The synthesis and reactivity of tetrazol-5-yl-phosphorus ylides towards N-halosuccinimide/TMSN(3) reagent systems was explored, opening the way to new haloazidoalkenes bearing a tetrazol-5-yl substituent. These compounds were obtained as single isomers, except in one case. X-ray crystal structures w...

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Detalles Bibliográficos
Autores principales: Cardoso, Ana L., Sousa, Carmo, Henriques, Marta S. C., Paixão, José A., Pinho e Melo, Teresa M. V. D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6332326/
https://www.ncbi.nlm.nih.gov/pubmed/26703533
http://dx.doi.org/10.3390/molecules201219848