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Copper-Catalyzed Dimerization/Cyclization of Itaconates

A copper-catalyzed domino reaction between itaconate esters and diethyl zinc (or silane) is developed, affording itaconate dimerization products, multi-ester-substituted cyclopentanones, in moderate to high yields.

Detalles Bibliográficos
Autores principales: Li, Zhiqiang, Li, Ruirui, Jiang, Lan, Li, Zhengning
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6332366/
https://www.ncbi.nlm.nih.gov/pubmed/26287154
http://dx.doi.org/10.3390/molecules200815023