Copper-Catalyzed Dimerization/Cyclization of Itaconates

A copper-catalyzed domino reaction between itaconate esters and diethyl zinc (or silane) is developed, affording itaconate dimerization products, multi-ester-substituted cyclopentanones, in moderate to high yields.

Detalles Bibliográficos
Autores principales: Li, Zhiqiang, Li, Ruirui, Jiang, Lan, Li, Zhengning
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2015
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6332366/
https://www.ncbi.nlm.nih.gov/pubmed/26287154
http://dx.doi.org/10.3390/molecules200815023
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author Li, Zhiqiang
Li, Ruirui
Jiang, Lan
Li, Zhengning
author_facet Li, Zhiqiang
Li, Ruirui
Jiang, Lan
Li, Zhengning
author_sort Li, Zhiqiang
collection PubMed
description A copper-catalyzed domino reaction between itaconate esters and diethyl zinc (or silane) is developed, affording itaconate dimerization products, multi-ester-substituted cyclopentanones, in moderate to high yields.
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spelling pubmed-63323662019-01-24 Copper-Catalyzed Dimerization/Cyclization of Itaconates Li, Zhiqiang Li, Ruirui Jiang, Lan Li, Zhengning Molecules Article A copper-catalyzed domino reaction between itaconate esters and diethyl zinc (or silane) is developed, affording itaconate dimerization products, multi-ester-substituted cyclopentanones, in moderate to high yields. MDPI 2015-08-17 /pmc/articles/PMC6332366/ /pubmed/26287154 http://dx.doi.org/10.3390/molecules200815023 Text en © 2015 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Li, Zhiqiang
Li, Ruirui
Jiang, Lan
Li, Zhengning
Copper-Catalyzed Dimerization/Cyclization of Itaconates
title Copper-Catalyzed Dimerization/Cyclization of Itaconates
title_full Copper-Catalyzed Dimerization/Cyclization of Itaconates
title_fullStr Copper-Catalyzed Dimerization/Cyclization of Itaconates
title_full_unstemmed Copper-Catalyzed Dimerization/Cyclization of Itaconates
title_short Copper-Catalyzed Dimerization/Cyclization of Itaconates
title_sort copper-catalyzed dimerization/cyclization of itaconates
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6332366/
https://www.ncbi.nlm.nih.gov/pubmed/26287154
http://dx.doi.org/10.3390/molecules200815023
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AT liruirui coppercatalyzeddimerizationcyclizationofitaconates
AT jianglan coppercatalyzeddimerizationcyclizationofitaconates
AT lizhengning coppercatalyzeddimerizationcyclizationofitaconates

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