Preparation and Reaction Chemistry of Novel Silicon-Substituted 1,3-Dienes

2-Silicon-substituted 1,3-dienes containing non transferrable groups known to promote transmetallation were prepared by Grignard chemistry and enyne metathesis. These dienes participated in one pot metathesis/Diels-Alder reactions in regio- and diastereoselective fashions. Electron-rich alkenes show...

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Detalles Bibliográficos
Autores principales: Choudhury, Partha P., Welker, Mark E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2015
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6332380/
https://www.ncbi.nlm.nih.gov/pubmed/26389877
http://dx.doi.org/10.3390/molecules200916892

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6332380/
https://www.ncbi.nlm.nih.gov/pubmed/26389877
http://dx.doi.org/10.3390/molecules200916892

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