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Sesquiterpene Synthase‐Catalysed Formation of a New Medium‐Sized Cyclic Terpenoid Ether from Farnesyl Diphosphate Analogues

Terpene synthases catalyse the first step in the conversion of prenyl diphosphates to terpenoids. They act as templates for their substrates to generate a reactive conformation, from which a Mg(2+)‐dependent reaction creates a carbocation–PP(i) ion pair that undergoes a series of rearrangements and...

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Detalles Bibliográficos
Autores principales: Huynh, Florence, Grundy, Daniel J., Jenkins, Robert L., Miller, David J., Allemann, Rudolf K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6334173/
https://www.ncbi.nlm.nih.gov/pubmed/29802753
http://dx.doi.org/10.1002/cbic.201800218