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Sesquiterpene Synthase‐Catalysed Formation of a New Medium‐Sized Cyclic Terpenoid Ether from Farnesyl Diphosphate Analogues
Terpene synthases catalyse the first step in the conversion of prenyl diphosphates to terpenoids. They act as templates for their substrates to generate a reactive conformation, from which a Mg(2+)‐dependent reaction creates a carbocation–PP(i) ion pair that undergoes a series of rearrangements and...
Autores principales: | Huynh, Florence, Grundy, Daniel J., Jenkins, Robert L., Miller, David J., Allemann, Rudolf K. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6334173/ https://www.ncbi.nlm.nih.gov/pubmed/29802753 http://dx.doi.org/10.1002/cbic.201800218 |
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