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Mechanistic studies of an L-proline-catalyzed pyridazine formation involving a Diels–Alder reaction with inverse electron demand

The mechanism of an L-proline-catalyzed pyridazine formation from acetone and aryl-substituted tetrazines via a Diels–Alder reaction with inverse electron demand has been studied with NMR and with electrospray ionization mass spectrometry. A catalytic cycle with three intermediates has been proposed...

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Detalles Bibliográficos
Autores principales: Schnell, Anne, Willms, J Alexander, Nozinovic, S, Engeser, Marianne
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6334817/
https://www.ncbi.nlm.nih.gov/pubmed/30680036
http://dx.doi.org/10.3762/bjoc.15.3