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Post synthetic exchange enables orthogonal click chemistry in a metal organic framework

Biphenyl-4,4′-dicarboxylic acid derivatives containing either azide or acetylene functional groups were inserted into UiO-67 metal organic frameworks (MOFs) via post synthetic linker exchange. Sequential and orthogonal click reactions could be performed on these modified MOFs by incubating the cryst...

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Detalles Bibliográficos
Autores principales: Fluch, Ulrike, McCarthy, Brian D., Ott, Sascha
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6336147/
https://www.ncbi.nlm.nih.gov/pubmed/30516766
http://dx.doi.org/10.1039/c8dt04563a