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Spectroscopic and Structural Study of Some Oligosilanylalkyne Complexes of Cobalt, Molybdenum and Nickel

Metal induced stabilization of α-carbocations is well known for cobalt- and molybdenum complexed propargyl cations. The same principle also allows access to reactivity enhancement of metal coordinated halo- and hydrosilylalkynes. In a previous study, we have shown that coordination of oligosilanylal...

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Detalles Bibliográficos
Autores principales: Zirngast, Michaela, Marschner, Christoph, Baumgartner, Judith
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6337173/
https://www.ncbi.nlm.nih.gov/pubmed/30626049
http://dx.doi.org/10.3390/molecules24010205