Rhodium(ii)-catalyzed C–H aminations using N-mesyloxycarbamates: reaction pathway and by-product formation

N-Mesyloxycarbamates are practical nitrene precursors that undergo C–H amination reactions in the presence of rhodium dimer catalysts. Under these conditions, both oxazolidinones and chiral amines have been prepared in a highly efficient manner. Given the elevated reactivity of the intermediates inv...

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Detalles Bibliográficos
Autores principales: Azek, Emna, Khalifa, Maroua, Bartholoméüs, Johan, Ernzerhof, Matthias, Lebel, Hélène
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6340404/
https://www.ncbi.nlm.nih.gov/pubmed/30746107
http://dx.doi.org/10.1039/c8sc03153c

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6340404/
https://www.ncbi.nlm.nih.gov/pubmed/30746107
http://dx.doi.org/10.1039/c8sc03153c

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