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Regioselective Manipulation of GlcNAc Provides Allosamine, Lividosamine, and Related Compounds
[Image: see text] Palladium-catalyzed oxidation of isopropyl N-acetyl-α-d-glucosamine (GlcNAc) is used to prepare the rare sugars allosamine, lividosamine, and related compounds with unprecedented selectivity. The Passerini reaction applied on 3-keto-GlcNAc provides an entry into branching of the ca...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2018
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6343366/ https://www.ncbi.nlm.nih.gov/pubmed/30569712 http://dx.doi.org/10.1021/acs.joc.8b01949 |