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Determination of the structure and geometry of N-heterocyclic carbenes on Au(111) using high-resolution spectroscopy
N-heterocyclic carbenes (NHCs) bind very strongly to transition metals due to their unique electronic structure featuring a divalent carbon atom with a lone pair in a highly directional sp(2)-hybridized orbital. As such, they can be assembled into monolayers on metal surfaces that have enhanced stab...
Autores principales: | , , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6346291/ https://www.ncbi.nlm.nih.gov/pubmed/30774887 http://dx.doi.org/10.1039/c8sc03502d |