Cargando…
Chemoselective α,β‐Dehydrogenation of Saturated Amides
We report a method for the selective α,β‐dehydrogenation of amides in the presence of other carbonyl moieties under mild conditions. Our strategy relies on electrophilic activation coupled to in situ selective selenium‐mediated dehydrogenation. The α,β‐unsaturated products were obtained in moderate...
Autores principales: | Teskey, Christopher J., Adler, Pauline, Gonçalves, Carlos R., Maulide, Nuno |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2018
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6348382/ https://www.ncbi.nlm.nih.gov/pubmed/30332524 http://dx.doi.org/10.1002/anie.201808794 |
Ejemplares similares
-
Unified
Approach to the Chemoselective α-Functionalization
of Amides with Heteroatom Nucleophiles
por: Gonçalves, Carlos R., et al.
Publicado: (2019) -
Chemoselective
Intermolecular Cross-Enolate-Type Coupling
of Amides
por: Kaiser, Daniel, et al.
Publicado: (2017) -
Chemoselective γ‐Oxidation of β,γ‐Unsaturated Amides with TEMPO
por: Heindl, Sebastian, et al.
Publicado: (2021) -
Chemoselective Alpha‐Deuteration of Amides via Retro‐ene Reaction
por: Porte, Vincent, et al.
Publicado: (2020) -
Chemoselective Activation of Diethyl Phosphonates: Modular Synthesis of Biologically Relevant Phosphonylated Scaffolds
por: Adler, Pauline, et al.
Publicado: (2018)