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Defying strain in the synthesis of an electroactive bilayer helicene

We report the synthesis of a bilayer chiral nanographene incorporating a [7]helicene scaffold and two perylene-diimide (PDI) subunits. Twofold visible-light-induced oxidative cyclization of a phenanthrene framework selects for the desired PDI-helicene, despite the immense strain that distinguishes t...

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Detalles Bibliográficos
Autores principales: Milton, Margarita, Schuster, Nathaniel J., Paley, Daniel W., Hernández Sánchez, Raúl, Ng, Fay, Steigerwald, Michael L., Nuckolls, Colin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6349016/
https://www.ncbi.nlm.nih.gov/pubmed/30774898
http://dx.doi.org/10.1039/c8sc04216k