Cargando…

Development and mechanistic investigation of the manganese(iii) salen-catalyzed dehydrogenation of alcohols

The first example of a manganese(iii) catalyst for the acceptorless dehydrogenation of alcohols is presented. N,N′-Bis(salicylidene)-1,2-cyclohexanediaminomanganese(iii) chloride (2) has been shown to catalyze the direct synthesis of imines from a variety of alcohols and amines with the liberation o...

Descripción completa

Detalles Bibliográficos
Autores principales: Samuelsen, Simone V., Santilli, Carola, Ahlquist, Mårten S. G., Madsen, Robert
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6349018/
https://www.ncbi.nlm.nih.gov/pubmed/30774913
http://dx.doi.org/10.1039/c8sc03969k