Ni-catalyzed migratory fluoro-alkenylation of unactivated alkyl bromides with gem-difluoroalkenes

We describe a nickel-catalyzed highly regio- and stereoselective migratory fluoro-alkenylation of unactivated alkyl bromides. A unique catalytic cycle merging alkyl nickel chain-walking and defluorinative coupling enables the introduction of a broad array of fluoroalkenyl moieties into carbon chains...

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Detalles Bibliográficos
Autores principales: Zhou, Lu, Zhu, Chuan, Bi, Peijia, Feng, Chao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6349022/
https://www.ncbi.nlm.nih.gov/pubmed/30774912
http://dx.doi.org/10.1039/c8sc04162h

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6349022/
https://www.ncbi.nlm.nih.gov/pubmed/30774912
http://dx.doi.org/10.1039/c8sc04162h

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