Reduction of organic azides by indyl-anions. Isolation and reactivity studies of indium–nitrogen multiple bonds

The synthesis of a new potassium–indyl complex, K[In(NON(Ar))] (NON(Ar) = [O(SiMe(2)NAr)(2)](2–), Ar = 2,6-(i)Pr(2)C(6)H(3)) and its reactivity with organic azides RN(3) is reported. When R = 2,6-bis(diphenylmethyl)-4-(t)Bu-phenyl, a dianionic alkyl-amide ligand is formed via C–H activation across a...

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Detalles Bibliográficos
Autores principales: Anker, Mathew D., Lein, Matthias, Coles, Martyn P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6349055/
https://www.ncbi.nlm.nih.gov/pubmed/30774921
http://dx.doi.org/10.1039/c8sc04078h

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6349055/
https://www.ncbi.nlm.nih.gov/pubmed/30774921
http://dx.doi.org/10.1039/c8sc04078h

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