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Alkynylation of graphene via the Sonogashira C–C cross-coupling reaction on fluorographene

We report successful grafting of alkynyl groups onto graphene via the Sonogashira reaction between fluorographene and terminal alkynes. Theoretical calculations revealed that fluorographene can efficiently bind and oxidize the palladium catalyst on electrophilic sites activated by fluorine atoms. Th...

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Detalles Bibliográficos
Autores principales: Chronopoulos, Demetrios D., Medved’, Miroslav, Błoński, Piotr, Nováček, Zdeněk, Jakubec, Petr, Tomanec, Ondřej, Bakandritsos, Aristides, Novotná, Veronika, Zbořil, Radek, Otyepka, Michal
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6350624/
https://www.ncbi.nlm.nih.gov/pubmed/30620024
http://dx.doi.org/10.1039/c8cc08492k