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Silanediol versus chlorosilanol: hydrolyses and hydrogen-bonding catalyses with fenchole-based silanes

Biphenyl-2,2’-bisfenchyloxydichlorosilane (7, BIFOXSiCl(2)) is synthesized and employed as precursor for the new silanols biphenyl-2,2’-bisfenchyloxychlorosilanol (8, BIFOXSiCl(OH)) and biphenyl-2,2’-bisfenchyloxysilanediol (9, BIFOXSi(OH)(2)). BIFOXSiCl(2) (7) shows a remarkable stability against h...

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Detalles Bibliográficos
Autores principales: Fox, Falco, Neudörfl, Jörg M, Goldfuss, Bernd
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6350884/
https://www.ncbi.nlm.nih.gov/pubmed/30745992
http://dx.doi.org/10.3762/bjoc.15.17