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Silanediol versus chlorosilanol: hydrolyses and hydrogen-bonding catalyses with fenchole-based silanes
Biphenyl-2,2’-bisfenchyloxydichlorosilane (7, BIFOXSiCl(2)) is synthesized and employed as precursor for the new silanols biphenyl-2,2’-bisfenchyloxychlorosilanol (8, BIFOXSiCl(OH)) and biphenyl-2,2’-bisfenchyloxysilanediol (9, BIFOXSi(OH)(2)). BIFOXSiCl(2) (7) shows a remarkable stability against h...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Beilstein-Institut
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6350884/ https://www.ncbi.nlm.nih.gov/pubmed/30745992 http://dx.doi.org/10.3762/bjoc.15.17 |