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Synthesis and Complexation of a Free Germanide Bearing a Tridentate N-Heterocyclic Substituent

[Image: see text] The tris-N-heterocycle germanide (tmim)Ge(–) (1) (tmimH(3) = tris(3-methylindol-2-yl)methane) was synthesized by nucleophilic substitution for the tmim(3–) trianion on GeCl(2)·dioxane. In combination with the previously reported (tmim)Si(–) and (tmim)P analogues, it provides a conv...

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Detalles Bibliográficos
Autores principales: Witteman, Léon, van Beek, Cody B., van Veenhuizen, Oscar N., Lutz, Martin, Moret, Marc-Etienne
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6354728/
https://www.ncbi.nlm.nih.gov/pubmed/30713362
http://dx.doi.org/10.1021/acs.organomet.8b00630