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Synthesis and Complexation of a Free Germanide Bearing a Tridentate N-Heterocyclic Substituent
[Image: see text] The tris-N-heterocycle germanide (tmim)Ge(–) (1) (tmimH(3) = tris(3-methylindol-2-yl)methane) was synthesized by nucleophilic substitution for the tmim(3–) trianion on GeCl(2)·dioxane. In combination with the previously reported (tmim)Si(–) and (tmim)P analogues, it provides a conv...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2019
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6354728/ https://www.ncbi.nlm.nih.gov/pubmed/30713362 http://dx.doi.org/10.1021/acs.organomet.8b00630 |