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Self-assembled M(12)L(24) nanospheres as a reaction vessel to facilitate a dinuclear Cu(i) catalyzed cyclization reaction
The application of large M(12)L(24) nanospheres allows the pre-concentration of catalysts to reach high local concentrations, facilitating reactions that proceed through dinuclear mechanisms. The mechanism of the copper(i)-catalyzed cyclization of 4-pentynoic acid has been elucidated by means of a d...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6354833/ https://www.ncbi.nlm.nih.gov/pubmed/30809346 http://dx.doi.org/10.1039/c8sc03767a |