F(10)BINOL-derived chiral phosphoric acid-catalyzed enantioselective carbonyl-ene reaction: theoretical elucidation of stereochemical outcomes

An F(10)BINOL-derived chiral phosphoric acid was shown to be an effective catalyst for an enantioselective carbonyl-ene reaction of 1,1-disubstituted olefins with ethyl glyoxylate as the common enophile. The perfluoro-binaphthyl skeleton is beneficial not only for adopting high catalytic activity bu...

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Detalles Bibliográficos
Autores principales: Kikuchi, Jun, Aramaki, Hiromu, Okamoto, Hiroshi, Terada, Masahiro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6354837/
https://www.ncbi.nlm.nih.gov/pubmed/30809359
http://dx.doi.org/10.1039/c8sc03587c

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6354837/
https://www.ncbi.nlm.nih.gov/pubmed/30809359
http://dx.doi.org/10.1039/c8sc03587c

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