Modulating proton diffusion and conductivity in metal–organic frameworks by incorporation of accessible free carboxylic acid groups

Three multi-carboxylic acid functionalised ligands have been designed, synthesised and utilised to prepare the new barium-based MOFs, MFM-510, -511, and -512, which show excellent stability to water-vapour. MFM-510 and MFM-511 show moderate proton conductivities (2.1 × 10(–5) and 5.1 × 10(–5) S cm(–...

Descripción completa

Detalles Bibliográficos
Autores principales: Rought, Peter, Marsh, Christopher, Pili, Simona, Silverwood, Ian P., Sakai, Victoria García, Li, Ming, Brown, Martyn S., Argent, Stephen P., Vitorica-Yrezabal, Inigo, Whitehead, George, Warren, Mark R., Yang, Sihai, Schröder, Martin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6354967/
https://www.ncbi.nlm.nih.gov/pubmed/30809366
http://dx.doi.org/10.1039/c8sc03022g

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6354967/
https://www.ncbi.nlm.nih.gov/pubmed/30809366
http://dx.doi.org/10.1039/c8sc03022g

Ejemplares similares