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Catalytic enantioselective construction of axial chirality in 1,3-disubstituted allenes
Metal-catalyzed enantioselective construction of the loosening axial allene chirality spreading over three carbon atoms using a chiral ligand is still a significant challenge. In the literature, steric effect of the substrates is the major strategy applied for such a purpose. Herein, we present a ge...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6355870/ https://www.ncbi.nlm.nih.gov/pubmed/30705274 http://dx.doi.org/10.1038/s41467-018-07908-1 |