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Catalytic enantioselective construction of axial chirality in 1,3-disubstituted allenes

Metal-catalyzed enantioselective construction of the loosening axial allene chirality spreading over three carbon atoms using a chiral ligand is still a significant challenge. In the literature, steric effect of the substrates is the major strategy applied for such a purpose. Herein, we present a ge...

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Detalles Bibliográficos
Autores principales: Song, Shihua, Zhou, Jing, Fu, Chunling, Ma, Shengming
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6355870/
https://www.ncbi.nlm.nih.gov/pubmed/30705274
http://dx.doi.org/10.1038/s41467-018-07908-1