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Solid-State Transformations in Inner Coordination Sphere of [Co(NH(3))(6)][Fe(C(2)O(4))(3)]∙3H(2)O as a Route to Access Catalytically Active Co-Fe Materials

Thermal decomposition of [Co(NH(3))(6)][Fe(C(2)O(4))(3)]∙3H(2)O in argon atmosphere, at a low heating rate (3°/min), and in large amounts of the initial complex (~0.1 mole), has been studied. It was possible to distinguish four decomposition steps upon heating: In the temperature range of 50–100 °C—...

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Detalles Bibliográficos
Autores principales: Domonov, Denis P., Pechenyuk, Sophia I., Semushina, Yulia P., Yusenko, Kirill V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6356322/
https://www.ncbi.nlm.nih.gov/pubmed/30634625
http://dx.doi.org/10.3390/ma12020221