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Solid-State Transformations in Inner Coordination Sphere of [Co(NH(3))(6)][Fe(C(2)O(4))(3)]∙3H(2)O as a Route to Access Catalytically Active Co-Fe Materials
Thermal decomposition of [Co(NH(3))(6)][Fe(C(2)O(4))(3)]∙3H(2)O in argon atmosphere, at a low heating rate (3°/min), and in large amounts of the initial complex (~0.1 mole), has been studied. It was possible to distinguish four decomposition steps upon heating: In the temperature range of 50–100 °C—...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6356322/ https://www.ncbi.nlm.nih.gov/pubmed/30634625 http://dx.doi.org/10.3390/ma12020221 |