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Disentangling the size-dependent geometric and electronic effects of palladium nanocatalysts beyond selectivity

The prominent size effect of metal nanoparticles shapes decisively nanocatalysis, but entanglement of the corresponding geometric and electronic effects prevents exploiting their distinct functionalities. In this work, we demonstrate that in palladium (Pd)–catalyzed aerobic oxidation of benzyl alcoh...

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Detalles Bibliográficos
Autores principales: Wang, Hengwei, Gu, Xiang-Kui, Zheng, Xusheng, Pan, Haibin, Zhu, Junfa, Chen, Si, Cao, Lina, Li, Wei-Xue, Lu, Junling
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Association for the Advancement of Science 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6357750/
https://www.ncbi.nlm.nih.gov/pubmed/30746440
http://dx.doi.org/10.1126/sciadv.aat6413