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Metal–salen molecular cages as efficient and recyclable heterogeneous catalysts for cycloaddition of CO(2) with epoxides under ambient conditions
A salen based molecular cage, salen@cage, was synthesized and complexed with Co and Al to yield metal–salen molecular cages, Co(ii)@cage, Co(iii)@cage and Al(iii)@cage. These cages were demonstrated to be efficient heterogeneous catalysts for the cycloaddition of CO(2) with styrene oxide, achieving...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6357855/ https://www.ncbi.nlm.nih.gov/pubmed/30809373 http://dx.doi.org/10.1039/c8sc05019h |