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Metal–salen molecular cages as efficient and recyclable heterogeneous catalysts for cycloaddition of CO(2) with epoxides under ambient conditions

A salen based molecular cage, salen@cage, was synthesized and complexed with Co and Al to yield metal–salen molecular cages, Co(ii)@cage, Co(iii)@cage and Al(iii)@cage. These cages were demonstrated to be efficient heterogeneous catalysts for the cycloaddition of CO(2) with styrene oxide, achieving...

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Autores principales: Ng, Chee Koon, Toh, Ren Wei, Lin, Ting Ting, Luo, He-Kuan, Hor, T. S. Andy, Wu, Jie
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6357855/
https://www.ncbi.nlm.nih.gov/pubmed/30809373
http://dx.doi.org/10.1039/c8sc05019h
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author Ng, Chee Koon
Toh, Ren Wei
Lin, Ting Ting
Luo, He-Kuan
Hor, T. S. Andy
Wu, Jie
author_facet Ng, Chee Koon
Toh, Ren Wei
Lin, Ting Ting
Luo, He-Kuan
Hor, T. S. Andy
Wu, Jie
author_sort Ng, Chee Koon
collection PubMed
description A salen based molecular cage, salen@cage, was synthesized and complexed with Co and Al to yield metal–salen molecular cages, Co(ii)@cage, Co(iii)@cage and Al(iii)@cage. These cages were demonstrated to be efficient heterogeneous catalysts for the cycloaddition of CO(2) with styrene oxide, achieving full conversion at 25 °C and 1 atm CO(2). Good to excellent yields of various cyclic carbonates were also achieved under mild conditions. Al(iii)@cage can be reused up to five times without any significant loss of its high catalytic activity. The capability to access a variety of heterogeneous organometallic catalysts with salen@cage offers new prospects for practical CO(2) utilization and chemical manufacturing.
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spelling pubmed-63578552019-02-26 Metal–salen molecular cages as efficient and recyclable heterogeneous catalysts for cycloaddition of CO(2) with epoxides under ambient conditions Ng, Chee Koon Toh, Ren Wei Lin, Ting Ting Luo, He-Kuan Hor, T. S. Andy Wu, Jie Chem Sci Chemistry A salen based molecular cage, salen@cage, was synthesized and complexed with Co and Al to yield metal–salen molecular cages, Co(ii)@cage, Co(iii)@cage and Al(iii)@cage. These cages were demonstrated to be efficient heterogeneous catalysts for the cycloaddition of CO(2) with styrene oxide, achieving full conversion at 25 °C and 1 atm CO(2). Good to excellent yields of various cyclic carbonates were also achieved under mild conditions. Al(iii)@cage can be reused up to five times without any significant loss of its high catalytic activity. The capability to access a variety of heterogeneous organometallic catalysts with salen@cage offers new prospects for practical CO(2) utilization and chemical manufacturing. Royal Society of Chemistry 2018-11-29 /pmc/articles/PMC6357855/ /pubmed/30809373 http://dx.doi.org/10.1039/c8sc05019h Text en This journal is © The Royal Society of Chemistry 2019 https://creativecommons.org/licenses/by/3.0/This article is freely available. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence (CC BY 3.0)
spellingShingle Chemistry
Ng, Chee Koon
Toh, Ren Wei
Lin, Ting Ting
Luo, He-Kuan
Hor, T. S. Andy
Wu, Jie
Metal–salen molecular cages as efficient and recyclable heterogeneous catalysts for cycloaddition of CO(2) with epoxides under ambient conditions
title Metal–salen molecular cages as efficient and recyclable heterogeneous catalysts for cycloaddition of CO(2) with epoxides under ambient conditions
title_full Metal–salen molecular cages as efficient and recyclable heterogeneous catalysts for cycloaddition of CO(2) with epoxides under ambient conditions
title_fullStr Metal–salen molecular cages as efficient and recyclable heterogeneous catalysts for cycloaddition of CO(2) with epoxides under ambient conditions
title_full_unstemmed Metal–salen molecular cages as efficient and recyclable heterogeneous catalysts for cycloaddition of CO(2) with epoxides under ambient conditions
title_short Metal–salen molecular cages as efficient and recyclable heterogeneous catalysts for cycloaddition of CO(2) with epoxides under ambient conditions
title_sort metal–salen molecular cages as efficient and recyclable heterogeneous catalysts for cycloaddition of co(2) with epoxides under ambient conditions
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6357855/
https://www.ncbi.nlm.nih.gov/pubmed/30809373
http://dx.doi.org/10.1039/c8sc05019h
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