Dual Geometry Schemes in Tetrel Bonds: Complexes between TF(4) (T = Si, Ge, Sn) and Pyridine Derivatives

When an N-base approaches the tetrel atom of TF(4) (T = Si, Ge, Sn) the latter molecule deforms from a tetrahedral structure in the monomer to a trigonal bipyramid. The base can situate itself at either an axial or equatorial position, leading to two different equilibrium geometries. The interaction...

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Detalles Bibliográficos
Autores principales: Zierkiewicz, Wiktor, Michalczyk, Mariusz, Wysokiński, Rafał, Scheiner, Steve
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6359171/
https://www.ncbi.nlm.nih.gov/pubmed/30669688
http://dx.doi.org/10.3390/molecules24020376

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6359171/
https://www.ncbi.nlm.nih.gov/pubmed/30669688
http://dx.doi.org/10.3390/molecules24020376

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