Crystal structures of [IrCl(2)(NHCHPh)((dppm)(C(N(2)dppm))-κ(3) P,C,P′)]Cl·5.5MeCN and [IrI(NHCHPh)(((dppm)C(N(2)))-κ(2) P,C)(dppm-κ(2) P,P′)]I(I(3))·0.5I(2)·MeOH·0.5CH(2)Cl(2): triazene fragmentation in a PCN pincer iridium complex

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